Development of an automatic method for americium and plutonium separation and preconcentration using an multisyringe flow injection analysis-multipumping flow system.

نویسندگان

  • Yamila Fajardo
  • Laura Ferrer
  • Enrique Gómez
  • Francesca Garcias
  • Monserrat Casas
  • Víctor Cerdà
چکیده

A new procedure for automatic separation and preconcentration of 241Am and 239+240Pu from interfering matrixes using transuranide (TRU)-resin is proposed. Combination of the multisyringe flow injection analysis and multipumping flow system techniques with the TRU-resin allows carrying out the sampling treatment and separation in a short time using large sample volumes. Americium is eluted from the column with 4 mol L(-1) hydrochloric acid, and then plutonium is separated via on-column Pu(IV) reduction to Pu(III) with titanium(III) chloride. The corresponding alpha activities are measured off-line, with a relative standard deviation of 3% and a lower limit of detection of 0.004 Bq mL(-1), by using a multiplanchet low-background proportional counter.

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عنوان ژورنال:
  • Analytical chemistry

دوره 80 1  شماره 

صفحات  -

تاریخ انتشار 2008